Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table

Vitaly Vitalevich Ovchinnikov

doi:doi:10.11648/j.ajpc.20130203.11

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Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table

Vitaly Vitalevich Ovchinnikov

Published in American Journal of Physical Chemistry (Volume 2, Issue 3)

Received: 16 July 2013 Published: 20 August 2013

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Abstract

It is necessary to note, that the heat of vaporization, all thermodynamic functions ∆с,fGo, ∆с,fHo, So, ∆cSocond and heat capacity (Cp) of organometallic compounds of I-IV groups of Mendeleev′s Periodic Table can be well characterized with the number of valence electrons N of them. It is difficult to do some conclusions relatively stoichiometric coefficients i and f in modified by us Kharasch equation vap,c,f,sΨo = i ± f *N as they concern to organometallic compounds of the different groups. Such conclusion can be made on settlement data of I and II groups only in our opinion. Nevertheless, 43 equations of this type have been created for the processes of vaporization, combustion, formation, entropic transformations and heat capacity. Probably, that such data will help with forecasting of thermochemical functions and parameters of yet not investigated organometallic compounds.

Published in	American Journal of Physical Chemistry (Volume 2, Issue 3)
DOI	10.11648/j.ajpc.20130203.11
Page(s)	52-59
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2013. Published by Science Publishing Group

Keywords

Organometallic Compounds, Free Energy of Combustion, Free Energy of Formation, Entropy, Heat Capacity, Heat of Combustion Heat of Formation

References

[1]	Ovchinnikov V.V., Thermochemistry of Heteroatomic Compounds: Interdependence between of some thermochemical Parameters of the different Classes of organic nitro compounds and a Number of valence Electrons in their Molecules, ACSJ, 3, 11-23 (2013).
[2]	Ovchinnikov V.V., Thermochemistry of Heteroatomic Compound: Some thermodynamic Aspects of Combustion and Formation of Carbohydrates of Different Structures, Chem. Journal. 2, 2, 59-65 (2013).
[3]	Kharasch M.S. and Sher B., The electronic conception of valence and heats of combustion of organic compounds, J. Phys. Chem., 25, 625-658(1925).
[4]	Ovchinnikov V.V., Thermochemistry of Heteroatomic Compounds: Enthalpy of Combustion of Organic Compounds of Group I–VII Elements, Doklady Physical Chemistry. 443, 49-52 (2012).
[5]	CoJ.D. and Pilcher G. Thermochemistry of Organic and Organometallic Compounds. Academic Press – London and New York, pp. 640 (1970).
[6]	Lebedev Yu.A. and Miroschnichenko E.A. Thermochemistry of vaporization of organic substances, Science, Moscow, pp. 215 (1981).
[7]	Liebman J.F., Martino Simoes J.A. and Slaydon S.W., In Lithium Chemistry: A Theoretical And Experimental Overview, Wiley, New York: Sapse A. M. and Schleyer P. von Rague, Eds. (1995).
[8]	Martinho Simões J.A., Private communication (see: http :// webbook. nist. gov/chemistry/om/).
[9]	Sheiman M.S., Nistratov V.P., Kamelova G.P. and Rabinovich I.B., Low-temperature heat capacity of organic compounds of aluminum and zinc, Probl. Kalorim. Khim. Termodin., Dokl. Vses. Konf., 10th, 2, 457-459 (1984).
[10]	Rabinovich I.B., Nistratov V.P., Fedoseev V.B., Sheiman M.S., Kamelova G.P., Karataev E.N. and Feshchenko I.A., Low-temperature specific heat and thermodynamic functions of diethylzinc, Zhur.Fiz. Khim. (Russ.), 62, 1349-1352 (1988).
[11]	Burchalova G.V., Kamelova G.P., Nistratov V.P., Sheiman M.S. and Rabinovich I.B., Low-temperature heat capacity of diethylmercury, Termodin. Org. Soedin.(Russ.), 7, 21-22 (1978).
[12]	Smith R.H. and Andrews D.H., Thermal energy studies. II. Phenyl derivatives of metals, J. Am. Chem. Soc., 53, 3661-3667 (1931).
[13]	Kostryukov V.N., Samorukov O.P., Samorukova N.Kh., Krasavin A.M. and Petrunin A.B., Heat capacity of triethylboron at low temperature, Vses. Konf. Kalorim., Russia, Tezisy Dokl. 7th, 2, 387-390 (1977).
[14]	McCullough J.P., Messerly J.F., Moore R.T. and Todd S.S., Trimethylaluminum: thermodynamic functions in the solid and liquid states, 0-380°K, vapor pressure, heat of vaporization, and entropy in the ideal gas state, J. Phys. Chem., 67, 677-679 (1963).
[15]	Rabinovich I.B., Nistratov V.P., Sheiman M.S., Klimov K.N., Kamelov G.P. and Zorin A.D., Specific heat and thermodynamic functions of triethylaluminium, Zhur. Fiz. Khim. (Russ.), 63, 522-x525 (1989).
[16]	Sheiman M.S., Rabinovich I.B., Nistratov V.P., Smirnova N.N., Kamelova G.P., Klimov K.N. and Zorin A.D., Low temperature heat capacity and thermodynamic functions of tripropylaluminum and diisobutylaluminum, Zhur. Fiz. Khim. (Russ.), 65, 831-836 (1991).
[17]	Pedley J.B. and Rylance J., Computer Analysed Thermochemical Data: Organicxand Organometallic Compounds, University of Sussex, Brigton (1977).
[18]	Stull D.R., Vapor Pressure of Pure Substances Organic Compounds, Ind. Eng. Chem., 39, 517-540 (1947).
[19]	Valerga A.J. and Kilpatrick J.E., Entropy related thermodynamic properties of tetramethylgermane, J. Chem. Phys., 52, 4545-4549 (1970).
[20]	Rabinovich I.B., Sheiman M.S., Nistratov V.P., Kamelova G.P. and Zorin A.D., The heat capacity and thermodynamic characteristics of tetraethylgermane, Zhur. Fiz. Khim. (Russ.), 59, 2414-2417 (1985).
[21]	Mogul P.H., Hochberg M.C., Michiel R., Nestel G.K., Wamsley B.L. and Coren S.D., Physical Properties of Tetra-n-alkylgermanes (C1-C6), J. Chem. Eng. Data, 19, 4-6 (1974).
[22]	Sheiman M.S., Rabinovich I.B., Nistratov V.P., Kamelova G.P., Karataev E.N. and Feshchenko I.A., Specific heat and thermodynamic haracteristics of tetramethylstanane, Zhur. Fiz. Khim., 63, 836-838 (1989).
[23]	Maslova V.A., Rabinovich I.B., Nistoalov V.P. and Faminskaya L.A., Specific heat and phase transitions of some alkyl compounds of silicon, germanium and tin, Tr. Khim. Khim. Tekhnol., (2), 44-50 (1972).
[24]	Adams G.P. and Carson A.S., The Enthalpy of Combustion of Organimetallic Compounds Measured with a Vacuum-jacketed Aneroud Calorimeter, The Enthalpy of Formation of Tin Tetraphenyl, J. Chem. Thermodyn., 1, 393-396 (1969).
[25]	Good W.D., Scott D.W., Lacina J.L. and McCullough J.P., Tetramethyllead: heat of formation by rotating-bomb calorimetry, J. Phys. Chem., 63, 1139-1142 (1959).
[26]	Stephenson R.M. and Malanowski S., Handbook of the Thermodynamics of Organic Compounds, Elsevier: New York (1987).
[27]	Data for General, Organic and Physical Chemistry. Copyright by C.D. Schaeffer, Jr. (Elizabethtown College), C.A. Strausser, M.W. and Thomsen C.H. Yoder (Franklin & Marshall College) (1989).
[28]	Karapetyanz M.Kh. and Karapetyanz M.L., The basic thermodynamic constants of inorga-nic and organic chemistry, Khimia, Moskow, pp. 471 (1968).
[29]	Ovchinnikov V.V., Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Some Thermodynamic Functions of Saturated Alkanes, ACSJ, in press (2013).

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Vitaly Vitalevich Ovchinnikov. (2013). Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table. American Journal of Physical Chemistry, 2(3), 52-59. https://doi.org/10.11648/j.ajpc.20130203.11

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ACS Style

Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table. Am. J. Phys. Chem. 2013, 2(3), 52-59. doi: 10.11648/j.ajpc.20130203.11

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AMA Style

Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table. Am J Phys Chem. 2013;2(3):52-59. doi: 10.11648/j.ajpc.20130203.11

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@article{10.11648/j.ajpc.20130203.11,
  author = {Vitaly Vitalevich Ovchinnikov},
  title = {Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table},
  journal = {American Journal of Physical Chemistry},
  volume = {2},
  number = {3},
  pages = {52-59},
  doi = {10.11648/j.ajpc.20130203.11},
  url = {https://doi.org/10.11648/j.ajpc.20130203.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20130203.11},
  abstract = {It is necessary to note, that the heat of vaporization, all thermodynamic functions ∆с,fGo, ∆с,fHo, So, ∆cSocond and heat capacity (Cp) of organometallic compounds of I-IV groups of Mendeleev′s Periodic Table can be well characterized with the number of valence electrons N of them. It is difficult to do some conclusions relatively stoichiometric coefficients i and f in modified by us Kharasch equation vap,c,f,sΨo = i ± f *N as they concern to organometallic compounds of the different groups. Such conclusion can be made on settlement data of I and II groups only in our opinion. Nevertheless, 43 equations of this type have been created for the processes of vaporization, combustion, formation, entropic transformations and heat capacity. Probably, that such data will help with forecasting of thermochemical functions and parameters of yet not investigated organometallic compounds.},
 year = {2013}
}

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TY  - JOUR
T1  - Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table
AU  - Vitaly Vitalevich Ovchinnikov
Y1  - 2013/08/20
PY  - 2013
N1  - https://doi.org/10.11648/j.ajpc.20130203.11
DO  - 10.11648/j.ajpc.20130203.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 52
EP  - 59
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20130203.11
AB  - It is necessary to note, that the heat of vaporization, all thermodynamic functions ∆с,fGo, ∆с,fHo, So, ∆cSocond and heat capacity (Cp) of organometallic compounds of I-IV groups of Mendeleev′s Periodic Table can be well characterized with the number of valence electrons N of them. It is difficult to do some conclusions relatively stoichiometric coefficients i and f in modified by us Kharasch equation vap,c,f,sΨo = i ± f *N as they concern to organometallic compounds of the different groups. Such conclusion can be made on settlement data of I and II groups only in our opinion. Nevertheless, 43 equations of this type have been created for the processes of vaporization, combustion, formation, entropic transformations and heat capacity. Probably, that such data will help with forecasting of thermochemical functions and parameters of yet not investigated organometallic compounds.
VL  - 2
IS  - 3
ER  -

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Author Information

Vitaly Vitalevich Ovchinnikov

Department of General Chemistry and Ecology, Tupolev Kazan National Researching Technical University, Tatarstan, Russia

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Vitaly Vitalevich Ovchinnikov. (2013). Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table. American Journal of Physical Chemistry, 2(3), 52-59. https://doi.org/10.11648/j.ajpc.20130203.11

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ACS Style

Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table. Am. J. Phys. Chem. 2013, 2(3), 52-59. doi: 10.11648/j.ajpc.20130203.11

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AMA Style

Vitaly Vitalevich Ovchinnikov. Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table. Am J Phys Chem. 2013;2(3):52-59. doi: 10.11648/j.ajpc.20130203.11

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@article{10.11648/j.ajpc.20130203.11,
  author = {Vitaly Vitalevich Ovchinnikov},
  title = {Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table},
  journal = {American Journal of Physical Chemistry},
  volume = {2},
  number = {3},
  pages = {52-59},
  doi = {10.11648/j.ajpc.20130203.11},
  url = {https://doi.org/10.11648/j.ajpc.20130203.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20130203.11},
  abstract = {It is necessary to note, that the heat of vaporization, all thermodynamic functions ∆с,fGo, ∆с,fHo, So, ∆cSocond and heat capacity (Cp) of organometallic compounds of I-IV groups of Mendeleev′s Periodic Table can be well characterized with the number of valence electrons N of them. It is difficult to do some conclusions relatively stoichiometric coefficients i and f in modified by us Kharasch equation vap,c,f,sΨo = i ± f *N as they concern to organometallic compounds of the different groups. Such conclusion can be made on settlement data of I and II groups only in our opinion. Nevertheless, 43 equations of this type have been created for the processes of vaporization, combustion, formation, entropic transformations and heat capacity. Probably, that such data will help with forecasting of thermochemical functions and parameters of yet not investigated organometallic compounds.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Thermochemistry of Heteroatomic Compounds: Analysis and Calculation of Thermodynamic Functions of Organometallic Compounds of I-IV Groups of Mendeleev′s Periodic Table
AU  - Vitaly Vitalevich Ovchinnikov
Y1  - 2013/08/20
PY  - 2013
N1  - https://doi.org/10.11648/j.ajpc.20130203.11
DO  - 10.11648/j.ajpc.20130203.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 52
EP  - 59
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20130203.11
AB  - It is necessary to note, that the heat of vaporization, all thermodynamic functions ∆с,fGo, ∆с,fHo, So, ∆cSocond and heat capacity (Cp) of organometallic compounds of I-IV groups of Mendeleev′s Periodic Table can be well characterized with the number of valence electrons N of them. It is difficult to do some conclusions relatively stoichiometric coefficients i and f in modified by us Kharasch equation vap,c,f,sΨo = i ± f *N as they concern to organometallic compounds of the different groups. Such conclusion can be made on settlement data of I and II groups only in our opinion. Nevertheless, 43 equations of this type have been created for the processes of vaporization, combustion, formation, entropic transformations and heat capacity. Probably, that such data will help with forecasting of thermochemical functions and parameters of yet not investigated organometallic compounds.
VL  - 2
IS  - 3
ER  -

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